Toxins Flock to Beads in a Scientific Tea Bag

Contaminants



19
Mar

Toxins Flock to Beads in a Scientific Tea Bag

By Ashleigh Papp When a New Zealand scientist shared a novel method to test water quality in the early 2000s that didn’t involve harvesting shellfish, UC Santa Cruz’ Raphael Kudela and his team of researchers quickly adopted the idea. After some fine-tuning, they named their new technique Solid Phase Adsorption Toxin Testing (SPATT, for short). The technique takes advantage of custom-built plastic, or resin, beads that are designed to absorb specific things. “It looks a lot like a tea bag,” says Kudela. So far, SPATT has been used to measure water quality from the Santa Cruz Wharf to the Berkeley Marina and at the mouths of the San Joaquin and Sacramento rivers.
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05
Mar

“The Bay is a jewel ― can you imagine if it stunk like it did in the ’50s or if it was green with algae?” asks retiring Executive Director of the Bay Area Clean Water Agencies (BACWA) David Williams, reflecting on his work over much of the last decade to address nutrient pollution.

Working with the 37 wastewater treatment plants that discharge into the Bay, as well as with the San Francisco Bay Regional Water Quality Control Board, Williams helped establish a science-based regional permit for nutrients from the plants. The forward-thinking permit includes nature-based solutions like using wastewater to nurture horizontal levees or create wetlands, buffering the Bay shore from crashing waves as the sea rises. “We have a very enlightened Water Board,” Williams says, “because of that, instead of fighting, the wastewater community is interested in collaborating.” Giving water agencies options lets them choose solutions that work best for them, combining the greatest efficacy with the lowest cost and the fewest unintended consequences. “It’s important to make sure water regulations are...
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22
Jan

Levels of pyrethroid insecticides spike sharply in the North Delta’s Cache Slough during winter rainstorms, rendering the water so toxic that it decimates laboratory populations of a half-inch crustacean called Hyalella azteca.

However, according to a study reported in the September 2019 San Francisco Estuary and Watershed Science, Hyalella collected in the wild from Cache Slough are resistant to pyrethroids. Genetic analysis revealed that, collectively, Hyalella in the slough have four mutations for pyrethroid resistance. They also have a fifth mutation for resistance to organophosphates and likely carbamates, two additional major classes of pesticides that are applied extensively on agricultural and urban lands. “Hyalella are special,” explains co-author Helen Poynton, a molecular ecotoxicologist at the University of Massachusetts in Boston. “They reproduce quickly and have a short life span, which makes them highly adaptable.” Pesticide interests have seized on findings of pyrethroid resistance in Hyalella elsewhere in the wild to argue that...
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22
Jan

A recent test found more than 250 chemicals in the Delta’s Cache Slough, but “Dr Doom” says figuring out what they all are, and their concentrations, is beside the point in our efforts to understand stressors on native fish resilience.

“Knowing the effect on the fish is more informative than knowing which chemicals may be causing it,” says UC Davis’ Richard Connon (whose colleagues gave him his sinister title), referring to taking an ecological rather than regulatory perspective on fish health, and also to the less obvious sublethal effects of contaminants on fish behavior and reproduction. Connon is the lead author of a wide-ranging journal article in the December 2019 issue of SFEWS on how to better focus contaminants research in the Delta, and how to use more advanced tools to get at the synergistic and additive effects of multiple contaminants and stressors. Despite decades of monitoring, gigabytes of available data, and significant regulatory oversight, there remains “major uncertainty” on...
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05
Dec

Speakers talk about emerging water quality issues such as stormwater management, contaminants in effluent, wastewater in Suisun Marsh, and nutrients discharged into the Bay.

Green Diet for Roads City of San Pablo project manager Amanda Booth went deep into the nitty gritty on green stormwater infrastructure at a State of the Estuary Conference session. “Talk to the utility agencies before you even start,” she said. “Read PG&E’s Greenbook guidelines. Know your city’s franchise agreements with gas, electrical, sewer, and water companies, figure out who pays to relocate facilities, for example, if that becomes necessary.” Changing the flow lines of runoff at the street, parcel and regional scale is what stormwater management via green infrastructure is all about. “Regional projects that treat regional drainage are the hardest to site,” said EOA Inc’s Chris Sommer during the session. “To build large stormwater retention projects at a...
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19
Sep

Tire Melt in Salmon Stream?

On the morning of November 8, 2018, Allen Harthorn, a farmer who lives near the town of Paradise, watched a dark cloud of smoke forming in the east and began to worry about the safety of his home. He also began to worry about some other residents of the Butte Creek watershed—the largest run of naturally spawned spring Chinook in California.
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19
Sep

Bay Not BPA-Free

By Ariel Rubissow Okamoto “BPA is globally detected in human urine,” says scientist Ila Shimabuku of the San Francisco Estuary Institute. BPA, one of a chemical group called bisphenols, is a clear, stable, durable ingredient in plastic bottles, can liners, cash register receipts and many other things we use and touch every day. In 2017, the RMP collected and analyzed 16 bisphenols (including bisphenol A, or BPA) in 22 water samples from around San Francisco Bay. Concentrations of BPA found were similar to those found in other marine and estuarine environments, and at levels approaching the threshold of ecotoxicity. “It’s an intriguing compound in terms of its mechanism for action on our health,” says the Institute’s lead scientist on emerging...
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17
Jun

Next Day Delivery: PCBs, Plastics, and Mercury All in One Package

The slow, downstream chemical migration of legacy contaminants like mercury and PCBs into the Bay is something that Lester McKee and his colleagues at the San Francisco Estuary Institute hope to cut short. “The sooner we can stop the inputs of these contaminants,” says SFEI’s Alicia Gilbreath, “the sooner the Bay can have a chance to recover.”
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17
Jun

Needed Now: A Big Blue-Green Push

From rain gardens to green streets to permeable parking lots and pebble dunes, landscape architects and resource managers are working to soften up shorelines and sidewalks, all to sponge up and filter stormwater runoff before it reaches the Estuary. This article details projects in the South Bay Salt Pond Project’s Eden Landing, Hayward’s Turner Court, and the Delta’s Elk Grove, and along the East Bay’s San Pablo Avenue and San Jose’s Chynoweth Avenue.
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Oakland green infrastructure vision.
14
Jun

Clock Ticking for Cities to Commit to Greening

Managing stormwater is a physics problem, and not a very glamorous one. In decades past, the main objective of managing stormwater was figuring out how fast it could be directed through the Bay Area’s built landscape via storm drains, culverts, and channels, and into the Bay. In decades future, however, the object will be to slow down the runoff, and sink it into greener, spongier surfaces sprinkled throughout our cities and counties, or to run it through more meandering, more natural channels and drainages. Such measures fall under the classification of green stormwater infrastructure. And building more green infrastructure isn’t just some kind of concept or vision. Instead, the region’s water quality regulators want to see more of it from...
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02
May

Melissa Foley’s list of concerns as the new head of San Francisco Bay’s premier water-quality program is long: microplastics, pharmaceuticals, PFASs, and other chemicals and contaminants entering the Bay through runoff and treated sewage.

An interdisciplinary scientist trained in marine ecology, with experience in policy, management, and public outreach, Foley assumed leadership late last year of the Regional Monitoring Program for Water Quality in San Francisco Bay (RMP). Along with overseeing the RMP’s rigorous efforts to study and manage Bay pollutants, Foley who comes to the RMP from New Zealand’s Auckland Council, where she used long-term environmental monitoring data to inform both regional and national management and policy strategies, says she’ll draw on her social-science background to include the public in the program’s work. That means calling upon citizens for data collection and getting them involved in improving the health of the Bay, right where they live or work. “We try to develop integrated...
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20
Mar

Getting a Bead on Table Salt

By Joe Eaton Microplastics are present in the San Francisco Bay, and at higher concentrations than Chesapeake Bay or the Great Lakes, according to a San Francisco Estuary Institute study led by Rebecca Sutton. There’s “a lot of uncertainty about potential impacts to people and wildlife,” she says.“[Miicroplastics are] a variable contaminant and challenging to interpret.” What we know is sufficient cause for concern: apart from their physical impacts, plastics can absorb other pollutants and some plastic ingredients are known endocrine disruptors. Cargill, the in-bay salt producer, says research is still determining the impact of microplastics on sea salt supplies but food safety remains a top priority.
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13
Feb

A marriage of robotics and artificial intelligence promises to automate the detection of harmful algal blooms, which can trigger shellfish harvesting bans and fill wildlife rescue centers with sickened animals.

The Imaging FlowCytobot (IFCB) takes water samples around the clock and photographs phytoplankton cells floating within. “It’s got a huge amount of potential for figuring out what plankton is in the water column and monitoring for HABs,” says Alexis Fischer, a postdoctoral fellow at the University of California, Santa Cruz with Raphael Kudela. Fischer and colleagues are building a phytoplankton image classifier already capable of identifying more than 90 percent of cells photographed by IFCB at the Santa Cruz Wharf. The bad actors really stand out in the crowd, Fischer says. “Many of the harmful algal bloom species tend to be larger and more uniquely shaped, which fortunately makes it easier for our classifier to distinguish them.” Phytoplankton from San Francisco...
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13
Dec

Saltwater Revival

“Swimming sustains me,” says Fran Hegeler of the South End Rowing Club. That’s the kind of enthusiastic language some Bay swimmers express, but sharing the water means sharing it in sickness and in health. Right now, Sausalito’s Marine Mammal Center is dealing with a large outbreak of leptospirosis, a bacterial infection that can cause fatal kidney damage in California sea lions. But it isn’t likely to affect swimmers, as the bacteria is not known to survive long in saltwater.
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13
Dec

Toxic Soup Strains Silos

Headlines about falsified tests are just the latest development in a long history of frustrations for Hunters Point in San Francisco. Recently, the neighborhood has been in the news due to fraud in the cleanup of the former Navy shipyard, contaminated with radioactive waste from nuclear research. In what is now called by some the biggest case of eco-fraud in U.S. history, 97 percent of the cleanup results are in question and two supervisors have been sentenced to prison.
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13
Dec

Medicating the Bay

“If you went to the doctor and told them you were taking 69 different pharmaceuticals,” says Emma Rosi of the Cary Institute of Ecosystem Studies, “they would be very concerned with your well-being.” When a study she co-authored detected that number of pharmaceutical compounds in caddisfly larvae along an Australian creek downstream of a treatment plant, it was further evidence that excreted drugs are escaping wastewater facilities and entering food webs. The Bay is no exception. A survey conducted by the San Francisco Estuary Institute found that seventeen commonly used drugs, including antibiotics, antidepressants, and over-the-counter painkillers, could exceed protective thresholds for marine life.
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13
Nov

In response to the critical threat that changing ocean chemistry poses to both ecosystems and economies, the California Ocean Protection Council adopted the state’s first Ocean Acidification Action Plan on October 25.

The plan addresses ocean acidification—like climate change, a consequence of rising atmospheric CO2 levels—in the context of other threats such as polluted runoff, warming temperatures, and rising seas. It promotes local solutions that are likely to provide multiple benefits—from improving water quality to promoting healthy seagrass, marsh, and kelp forest habitats. The plan, one of the first released by a member of the International Alliance to Combat Ocean Acidification, identifies six key strategies, and outlines five-year goals and actions for each. “We hope this plan can serve as a model for other jurisdictions that are looking to address ocean acidification and global ocean change through concrete and targeted local, regional, multidisciplinary and scalable activities,” says the Council’s Jennifer Phillips. CHT
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13
Nov

Recent discoveries are promising new weapons against red tides, the massive blooms of microscopic marine algae that are notorious for playing havoc with marine ecosystems.

The culprit behind poisoned seabirds, closed crab fisheries, stranded sea lions, and shellfish poisoning in humans are often diatoms producing the neurotoxin domoic acid. Now, scientists have identified the genes and biochemical processes responsible in diatoms of the genus Pseudo-nitzschia. The finding, published in the journal Science, opens the door to rapid genetic monitoring of algal blooms as a means to spot nascent harmful blooms and track their spread. “By identifying the genes that encode domoic acid production, we are now able to ask questions about what ocean conditions turn these genes on or off,” said lead author Patrick Brunson of the Scripps Institution of Oceanography. The achievement comes not a moment too soon: with algal blooms getting larger and...
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26
Sep

Cigarette Butts Still the Number One Item in Coastal Trash

The number one item still found in California’s beach and coast clean ups is cigarette butts, according to Surfrider’s San Francisco chapter director Shelley Ericksen. Surfrider’s “Hold-on-to-your-Butt” campaign, launched in 1992, and local law enforcement have failed to make a dent in the habit of smokers tossing their butts anywhere they please, and this isn’t good for the environment. A 2011 study in the journal Tobacco Control showed that a single butt in a liter of water can lethally poison fish; on a more local level, San Francisco Estuary Institute studies have found that estuary waters contain anywhere from two to ten times as many microplastic particles (cigarette filters are made of plastic) as samples from Chesapeake Bay on the...
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26
Sep

San Joaquin Communities Access Cleaner Water Due to New Legislation

The only water easily available to many low-income inhabitants of the San Joaquin Valley’s smaller, non-incorporated settlements is well water tainted with arsenic and nitrates from surrounding activities. But two state bills ensure that these communities – and everyone else in California – not only have the right to safe, clean, and affordable drinking water, but also get access to public water infrastructure and services as needed. Assembly Bill 2501, approved this fall, “makes sure the state’s consolidation authority can order a city or special district to extend clean drinking water services to people in domestic dwellings,” says Phoebe Seaton of the Leadership Counsel for Justice and Accountability. Advocacy on the part of affected communities, with help from organizations like...
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